|
University of Jos Institutional Repository >
Natural Sciences >
Chemistry >
Please use this identifier to cite or link to this item:
http://hdl.handle.net/123456789/717
|
| Title: | Kinetics and Mechanism of the Oxidation of Acetaldehyde by Bromate ion in Aqueous Perchloric Acid |
| Authors: | Lohdip, Y.N
Davies, A.K
Iyun, J.F |
| Issue Date: | 1996 |
| Publisher: | Nigerian Journal of Medical Research |
| Series/Report no.: | Vol.1;Pp 49-52 |
| Abstract: | The stoichiometry, kinetics and mechanism of the oxidation of acetaldehyde by bromate ion in aqueous perchloric acid have been investigated. The reaction follows the empirical rate law; -d{CH2CHO}/dt={a+b[H+]} [BrO3] Where a=2.14x10-2M1g-1, b=2.7) x 10-1M-2g-1 at 23.0+0.1C, {H+}=0.05-0.15M and I=1.0M(NaC104). The mechanism of the reaction is discussed in terms of the outer-sphere mechanism. |
| URI: | http://hdl.handle.net/123456789/717 |
| Appears in Collections: | Chemistry
|
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
|
